<data xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">
<row _id="1"><Sample>Mixed PFAS</Sample><Purified by HPLC Fraction Collector?>No</Purified by HPLC Fraction Collector?><Concentration for Orbitrap-IRMS (mM)>5</Concentration for Orbitrap-IRMS (mM)><Starting Matrix>Methanol</Starting Matrix><d13C Replicate 1 (%0)>-26.5</d13C Replicate 1 (%0)><d13C Replicate 2 (%0)>-26.7</d13C Replicate 2 (%0)><d13C Replicate 3 (%0)>-26.9</d13C Replicate 3 (%0)><d13C Replicate 4 (%0)>-27.4</d13C Replicate 4 (%0)><d13C Replicate 5 (%0)>-27.2</d13C Replicate 5 (%0)><d13C Replicate 6 (%0)>-28.0</d13C Replicate 6 (%0)><d13C Replicate 7 (%0)>-27.7</d13C Replicate 7 (%0)><d13C Replicate 8 (%0)>-26.3</d13C Replicate 8 (%0)><d13C Replicate 9 (%0)>-26.1</d13C Replicate 9 (%0)><d13C Replicate 10 (%0)>-27.0</d13C Replicate 10 (%0)><d13C Replicate 11 (%0)>-26.8</d13C Replicate 11 (%0)><d13C Replicate 12 (%0) xsi:nil="true" /><d13C Replicate 13 (%0) xsi:nil="true" /><d13C Replicate 14 (%0) xsi:nil="true" /><d13C Replicate 15 (%0) xsi:nil="true" /><d13C Replicate 16 (%0) xsi:nil="true" /><d13C Replicate 17 (%0) xsi:nil="true" /><d13C Replicate 18 (%0) xsi:nil="true" /><Average d13C  (%0)>-27.0</Average d13C  (%0)><d13C STDEV  (%0)>0.6</d13C STDEV  (%0)><Offset from EA-IRMS d13C  (%0)>-0.1</Offset from EA-IRMS d13C  (%0)></row>
<row _id="2"><Sample>Fluoryx 0020TC</Sample><Purified by HPLC Fraction Collector?>Yes</Purified by HPLC Fraction Collector?><Concentration for Orbitrap-IRMS (mM)>5</Concentration for Orbitrap-IRMS (mM)><Starting Matrix>Methanol</Starting Matrix><d13C Replicate 1 (%0)>-27.2</d13C Replicate 1 (%0)><d13C Replicate 2 (%0)>-27.5</d13C Replicate 2 (%0)><d13C Replicate 3 (%0)>-27.6</d13C Replicate 3 (%0)><d13C Replicate 4 (%0)>-27.8</d13C Replicate 4 (%0)><d13C Replicate 5 (%0)>-27.3</d13C Replicate 5 (%0)><d13C Replicate 6 (%0)>-27.2</d13C Replicate 6 (%0)><d13C Replicate 7 (%0)>-26.0</d13C Replicate 7 (%0)><d13C Replicate 8 (%0)>-25.8</d13C Replicate 8 (%0)><d13C Replicate 9 (%0)>-24.6</d13C Replicate 9 (%0)><d13C Replicate 10 (%0)>-25.7</d13C Replicate 10 (%0)><d13C Replicate 11 (%0)>-26.9</d13C Replicate 11 (%0)><d13C Replicate 12 (%0)>-26.0</d13C Replicate 12 (%0)><d13C Replicate 13 (%0)>-26.5</d13C Replicate 13 (%0)><d13C Replicate 14 (%0)>-26.7</d13C Replicate 14 (%0)><d13C Replicate 15 (%0)>-26.7</d13C Replicate 15 (%0)><d13C Replicate 16 (%0)>-26.2</d13C Replicate 16 (%0)><d13C Replicate 17 (%0)>-27.6</d13C Replicate 17 (%0)><d13C Replicate 18 (%0)>-27.1</d13C Replicate 18 (%0)><Average d13C  (%0)>-26.7</Average d13C  (%0)><d13C STDEV  (%0)>0.8</d13C STDEV  (%0)><Offset from EA-IRMS d13C  (%0)>0.2</Offset from EA-IRMS d13C  (%0)></row>
<row _id="3"><Sample>SynQuest 00022778</Sample><Purified by HPLC Fraction Collector?>Yes</Purified by HPLC Fraction Collector?><Concentration for Orbitrap-IRMS (mM)>5</Concentration for Orbitrap-IRMS (mM)><Starting Matrix>Methanol</Starting Matrix><d13C Replicate 1 (%0)>-46.3</d13C Replicate 1 (%0)><d13C Replicate 2 (%0)>-45.8</d13C Replicate 2 (%0)><d13C Replicate 3 (%0)>-46.0</d13C Replicate 3 (%0)><d13C Replicate 4 (%0)>-46.8</d13C Replicate 4 (%0)><d13C Replicate 5 (%0)>-46.2</d13C Replicate 5 (%0)><d13C Replicate 6 (%0)>-46.1</d13C Replicate 6 (%0)><d13C Replicate 7 (%0)>-46.7</d13C Replicate 7 (%0)><d13C Replicate 8 (%0)>-46.8</d13C Replicate 8 (%0)><d13C Replicate 9 (%0)>-47.7</d13C Replicate 9 (%0)><d13C Replicate 10 (%0)>-46.6</d13C Replicate 10 (%0)><d13C Replicate 11 (%0)>-46.5</d13C Replicate 11 (%0)><d13C Replicate 12 (%0)>-46.9</d13C Replicate 12 (%0)><d13C Replicate 13 (%0)>-44.9</d13C Replicate 13 (%0)><d13C Replicate 14 (%0)>-43.5</d13C Replicate 14 (%0)><d13C Replicate 15 (%0)>-44.7</d13C Replicate 15 (%0)><d13C Replicate 16 (%0)>-45.7</d13C Replicate 16 (%0)><d13C Replicate 17 (%0)>-46.3</d13C Replicate 17 (%0)><d13C Replicate 18 (%0)>-45.3</d13C Replicate 18 (%0)><Average d13C  (%0)>-46.1</Average d13C  (%0)><d13C STDEV  (%0)>1.0</d13C STDEV  (%0)><Offset from EA-IRMS d13C  (%0)>0.0</Offset from EA-IRMS d13C  (%0)></row>
<row _id="4"><Sample>Mixed PFAS</Sample><Purified by HPLC Fraction Collector?>Yes</Purified by HPLC Fraction Collector?><Concentration for Orbitrap-IRMS (mM)>5</Concentration for Orbitrap-IRMS (mM)><Starting Matrix>Methanol</Starting Matrix><d13C Replicate 1 (%0)>-26.9</d13C Replicate 1 (%0)><d13C Replicate 2 (%0)>-27.3</d13C Replicate 2 (%0)><d13C Replicate 3 (%0)>-27.5</d13C Replicate 3 (%0)><d13C Replicate 4 (%0)>-27.2</d13C Replicate 4 (%0)><d13C Replicate 5 (%0)>-27.0</d13C Replicate 5 (%0)><d13C Replicate 6 (%0)>-27.2</d13C Replicate 6 (%0)><d13C Replicate 7 (%0)>-26.2</d13C Replicate 7 (%0)><d13C Replicate 8 (%0)>-25.9</d13C Replicate 8 (%0)><d13C Replicate 9 (%0)>-26.1</d13C Replicate 9 (%0)><d13C Replicate 10 (%0)>-26.6</d13C Replicate 10 (%0)><d13C Replicate 11 (%0)>-26.1</d13C Replicate 11 (%0)><d13C Replicate 12 (%0)>-25.9</d13C Replicate 12 (%0)><d13C Replicate 13 (%0)>-27.9</d13C Replicate 13 (%0)><d13C Replicate 14 (%0)>-27.6</d13C Replicate 14 (%0)><d13C Replicate 15 (%0)>-26.8</d13C Replicate 15 (%0)><d13C Replicate 16 (%0)>-27.6</d13C Replicate 16 (%0)><d13C Replicate 17 (%0)>-27.3</d13C Replicate 17 (%0)><d13C Replicate 18 (%0)>-27.2</d13C Replicate 18 (%0)><Average d13C  (%0)>-26.9</Average d13C  (%0)><d13C STDEV  (%0)>0.6</d13C STDEV  (%0)><Offset from EA-IRMS d13C  (%0)>0.0</Offset from EA-IRMS d13C  (%0)></row>
<row _id="5"><Sample>Mixed PFAS</Sample><Purified by HPLC Fraction Collector?>Yes</Purified by HPLC Fraction Collector?><Concentration for Orbitrap-IRMS (mM)>2</Concentration for Orbitrap-IRMS (mM)><Starting Matrix>Methanol</Starting Matrix><d13C Replicate 1 (%0)>-27.6</d13C Replicate 1 (%0)><d13C Replicate 2 (%0)>-26.7</d13C Replicate 2 (%0)><d13C Replicate 3 (%0)>-28.3</d13C Replicate 3 (%0)><d13C Replicate 4 (%0)>-25.7</d13C Replicate 4 (%0)><d13C Replicate 5 (%0)>-26.9</d13C Replicate 5 (%0)><d13C Replicate 6 (%0)>-26.6</d13C Replicate 6 (%0)><d13C Replicate 7 (%0)>-26.3</d13C Replicate 7 (%0)><d13C Replicate 8 (%0)>-26.4</d13C Replicate 8 (%0)><d13C Replicate 9 (%0)>-25.0</d13C Replicate 9 (%0)><d13C Replicate 10 (%0)>-26.3</d13C Replicate 10 (%0)><d13C Replicate 11 (%0)>-27.0</d13C Replicate 11 (%0)><d13C Replicate 12 (%0)>-26.7</d13C Replicate 12 (%0)><d13C Replicate 13 (%0)>-27.6</d13C Replicate 13 (%0)><d13C Replicate 14 (%0)>-27.0</d13C Replicate 14 (%0)><d13C Replicate 15 (%0)>-25.8</d13C Replicate 15 (%0)><d13C Replicate 16 (%0)>-26.5</d13C Replicate 16 (%0)><d13C Replicate 17 (%0)>-26.4</d13C Replicate 17 (%0)><d13C Replicate 18 (%0)>-26.9</d13C Replicate 18 (%0)><Average d13C  (%0)>-26.7</Average d13C  (%0)><d13C STDEV  (%0)>0.8</d13C STDEV  (%0)><Offset from EA-IRMS d13C  (%0)>0.2</Offset from EA-IRMS d13C  (%0)></row>
<row _id="6"><Sample>Mixed PFAS</Sample><Purified by HPLC Fraction Collector?>Yes</Purified by HPLC Fraction Collector?><Concentration for Orbitrap-IRMS (mM)>1</Concentration for Orbitrap-IRMS (mM)><Starting Matrix>Methanol</Starting Matrix><d13C Replicate 1 (%0)>-28.1</d13C Replicate 1 (%0)><d13C Replicate 2 (%0)>-27.3</d13C Replicate 2 (%0)><d13C Replicate 3 (%0)>-28.2</d13C Replicate 3 (%0)><d13C Replicate 4 (%0)>-26.2</d13C Replicate 4 (%0)><d13C Replicate 5 (%0)>-27.6</d13C Replicate 5 (%0)><d13C Replicate 6 (%0)>-27.6</d13C Replicate 6 (%0)><d13C Replicate 7 (%0)>-26.4</d13C Replicate 7 (%0)><d13C Replicate 8 (%0)>-27.1</d13C Replicate 8 (%0)><d13C Replicate 9 (%0)>-26.7</d13C Replicate 9 (%0)><d13C Replicate 10 (%0)>-27.4</d13C Replicate 10 (%0)><d13C Replicate 11 (%0)>-26.9</d13C Replicate 11 (%0)><d13C Replicate 12 (%0)>-27.0</d13C Replicate 12 (%0)><d13C Replicate 13 (%0) xsi:nil="true" /><d13C Replicate 14 (%0) xsi:nil="true" /><d13C Replicate 15 (%0) xsi:nil="true" /><d13C Replicate 16 (%0) xsi:nil="true" /><d13C Replicate 17 (%0) xsi:nil="true" /><d13C Replicate 18 (%0) xsi:nil="true" /><Average d13C  (%0)>-27.2</Average d13C  (%0)><d13C STDEV  (%0)>0.6</d13C STDEV  (%0)><Offset from EA-IRMS d13C  (%0)>-0.3</Offset from EA-IRMS d13C  (%0)></row>
<row _id="7"><Sample>CMS Dock Spiked</Sample><Purified by HPLC Fraction Collector?>Yes</Purified by HPLC Fraction Collector?><Concentration for Orbitrap-IRMS (mM)>5</Concentration for Orbitrap-IRMS (mM)><Starting Matrix>Seawater</Starting Matrix><d13C Replicate 1 (%0)>-26.6</d13C Replicate 1 (%0)><d13C Replicate 2 (%0)>-27.6</d13C Replicate 2 (%0)><d13C Replicate 3 (%0)>-27.6</d13C Replicate 3 (%0)><d13C Replicate 4 (%0)>-27.4</d13C Replicate 4 (%0)><d13C Replicate 5 (%0)>-26.0</d13C Replicate 5 (%0)><d13C Replicate 6 (%0)>-27.4</d13C Replicate 6 (%0)><d13C Replicate 7 (%0)>-26.6</d13C Replicate 7 (%0)><d13C Replicate 8 (%0)>-26.9</d13C Replicate 8 (%0)><d13C Replicate 9 (%0)>-25.9</d13C Replicate 9 (%0)><d13C Replicate 10 (%0)>-25.4</d13C Replicate 10 (%0)><d13C Replicate 11 (%0)>-25.9</d13C Replicate 11 (%0)><d13C Replicate 12 (%0)>-25.7</d13C Replicate 12 (%0)><d13C Replicate 13 (%0)>-27.6</d13C Replicate 13 (%0)><d13C Replicate 14 (%0)>-27.4</d13C Replicate 14 (%0)><d13C Replicate 15 (%0)>-28.2</d13C Replicate 15 (%0)><d13C Replicate 16 (%0)>-28.6</d13C Replicate 16 (%0)><d13C Replicate 17 (%0)>-28.0</d13C Replicate 17 (%0)><d13C Replicate 18 (%0)>-28.4</d13C Replicate 18 (%0)><Average d13C  (%0)>-27.1</Average d13C  (%0)><d13C STDEV  (%0)>1.0</d13C STDEV  (%0)><Offset from EA-IRMS d13C  (%0)>-0.2</Offset from EA-IRMS d13C  (%0)></row>
<row _id="8"><Sample>WD182 Spiked</Sample><Purified by HPLC Fraction Collector?>Yes</Purified by HPLC Fraction Collector?><Concentration for Orbitrap-IRMS (mM)>5</Concentration for Orbitrap-IRMS (mM)><Starting Matrix>Rainwater</Starting Matrix><d13C Replicate 1 (%0)>-27.1</d13C Replicate 1 (%0)><d13C Replicate 2 (%0)>-27.3</d13C Replicate 2 (%0)><d13C Replicate 3 (%0)>-27.7</d13C Replicate 3 (%0)><d13C Replicate 4 (%0)>-26.9</d13C Replicate 4 (%0)><d13C Replicate 5 (%0)>-27.5</d13C Replicate 5 (%0)><d13C Replicate 6 (%0)>-27.4</d13C Replicate 6 (%0)><d13C Replicate 7 (%0)>-27.5</d13C Replicate 7 (%0)><d13C Replicate 8 (%0)>-27.6</d13C Replicate 8 (%0)><d13C Replicate 9 (%0)>-27.8</d13C Replicate 9 (%0)><d13C Replicate 10 (%0)>-27.1</d13C Replicate 10 (%0)><d13C Replicate 11 (%0)>-28.2</d13C Replicate 11 (%0)><d13C Replicate 12 (%0)>-27.8</d13C Replicate 12 (%0)><d13C Replicate 13 (%0)>-27.2</d13C Replicate 13 (%0)><d13C Replicate 14 (%0)>-27.6</d13C Replicate 14 (%0)><d13C Replicate 15 (%0)>-28.0</d13C Replicate 15 (%0)><d13C Replicate 16 (%0)>-27.8</d13C Replicate 16 (%0)><d13C Replicate 17 (%0)>-27.8</d13C Replicate 17 (%0)><d13C Replicate 18 (%0)>-27.7</d13C Replicate 18 (%0)><Average d13C  (%0)>-27.6</Average d13C  (%0)><d13C STDEV  (%0)>0.3</d13C STDEV  (%0)><Offset from EA-IRMS d13C  (%0)>-0.7</Offset from EA-IRMS d13C  (%0)></row>
<row _id="9"><Sample>Cape Fear River Spiked</Sample><Purified by HPLC Fraction Collector?>Yes</Purified by HPLC Fraction Collector?><Concentration for Orbitrap-IRMS (mM)>5</Concentration for Orbitrap-IRMS (mM)><Starting Matrix>Freshwater</Starting Matrix><d13C Replicate 1 (%0)>-27.3</d13C Replicate 1 (%0)><d13C Replicate 2 (%0)>-27.5</d13C Replicate 2 (%0)><d13C Replicate 3 (%0)>-27.6</d13C Replicate 3 (%0)><d13C Replicate 4 (%0)>-26.9</d13C Replicate 4 (%0)><d13C Replicate 5 (%0)>-27.0</d13C Replicate 5 (%0)><d13C Replicate 6 (%0)>-27.5</d13C Replicate 6 (%0)><d13C Replicate 7 (%0)>-27.0</d13C Replicate 7 (%0)><d13C Replicate 8 (%0)>-26.8</d13C Replicate 8 (%0)><d13C Replicate 9 (%0)>-26.8</d13C Replicate 9 (%0)><d13C Replicate 10 (%0)>-26.6</d13C Replicate 10 (%0)><d13C Replicate 11 (%0)>-27.0</d13C Replicate 11 (%0)><d13C Replicate 12 (%0)>-26.9</d13C Replicate 12 (%0)><d13C Replicate 13 (%0)>-26.2</d13C Replicate 13 (%0)><d13C Replicate 14 (%0)>-26.0</d13C Replicate 14 (%0)><d13C Replicate 15 (%0)>-26.7</d13C Replicate 15 (%0)><d13C Replicate 16 (%0)>-27.0</d13C Replicate 16 (%0)><d13C Replicate 17 (%0)>-26.9</d13C Replicate 17 (%0)><d13C Replicate 18 (%0)>-26.9</d13C Replicate 18 (%0)><Average d13C  (%0)>-26.9</Average d13C  (%0)><d13C STDEV  (%0)>0.4</d13C STDEV  (%0)><Offset from EA-IRMS d13C  (%0)>0.0</Offset from EA-IRMS d13C  (%0)></row>
<row _id="10"><Sample>Sample 1 (non-spiked)</Sample><Purified by HPLC Fraction Collector?>Yes</Purified by HPLC Fraction Collector?><Concentration for Orbitrap-IRMS (mM) xsi:nil="true" /><Starting Matrix>Freshwater</Starting Matrix><d13C Replicate 1 (%0)>-41.4</d13C Replicate 1 (%0)><d13C Replicate 2 (%0)>-41.5</d13C Replicate 2 (%0)><d13C Replicate 3 (%0)>-42.7</d13C Replicate 3 (%0)><d13C Replicate 4 (%0)>-42.6</d13C Replicate 4 (%0)><d13C Replicate 5 (%0)>-40.2</d13C Replicate 5 (%0)><d13C Replicate 6 (%0)>-40.1</d13C Replicate 6 (%0)><d13C Replicate 7 (%0)>-39.0</d13C Replicate 7 (%0)><d13C Replicate 8 (%0)>-39.3</d13C Replicate 8 (%0)><d13C Replicate 9 (%0)>-39.4</d13C Replicate 9 (%0)><d13C Replicate 10 (%0)>-39.9</d13C Replicate 10 (%0)><d13C Replicate 11 (%0)>-40.5</d13C Replicate 11 (%0)><d13C Replicate 12 (%0)>-40.1</d13C Replicate 12 (%0)><d13C Replicate 13 (%0)>-39.7</d13C Replicate 13 (%0)><d13C Replicate 14 (%0)>-39.5</d13C Replicate 14 (%0)><d13C Replicate 15 (%0)>-39.9</d13C Replicate 15 (%0)><d13C Replicate 16 (%0)>-40.3</d13C Replicate 16 (%0)><d13C Replicate 17 (%0) xsi:nil="true" /><d13C Replicate 18 (%0) xsi:nil="true" /><Average d13C  (%0)>-40.4</Average d13C  (%0)><d13C STDEV  (%0)>1.1</d13C STDEV  (%0)><Offset from EA-IRMS d13C  (%0) xsi:nil="true" /></row>
<row _id="11"><Sample>Sample 2 (non-spiked)</Sample><Purified by HPLC Fraction Collector?>Yes</Purified by HPLC Fraction Collector?><Concentration for Orbitrap-IRMS (mM) xsi:nil="true" /><Starting Matrix>Freshwater</Starting Matrix><d13C Replicate 1 (%0)>-42.1</d13C Replicate 1 (%0)><d13C Replicate 2 (%0)>-41.4</d13C Replicate 2 (%0)><d13C Replicate 3 (%0)>-41.2</d13C Replicate 3 (%0)><d13C Replicate 4 (%0)>-41.8</d13C Replicate 4 (%0)><d13C Replicate 5 (%0)>-42.2</d13C Replicate 5 (%0)><d13C Replicate 6 (%0)>-41.9</d13C Replicate 6 (%0)><d13C Replicate 7 (%0) xsi:nil="true" /><d13C Replicate 8 (%0) xsi:nil="true" /><d13C Replicate 9 (%0) xsi:nil="true" /><d13C Replicate 10 (%0) xsi:nil="true" /><d13C Replicate 11 (%0) xsi:nil="true" /><d13C Replicate 12 (%0) xsi:nil="true" /><d13C Replicate 13 (%0) xsi:nil="true" /><d13C Replicate 14 (%0) xsi:nil="true" /><d13C Replicate 15 (%0) xsi:nil="true" /><d13C Replicate 16 (%0) xsi:nil="true" /><d13C Replicate 17 (%0) xsi:nil="true" /><d13C Replicate 18 (%0) xsi:nil="true" /><Average d13C  (%0)>-41.8</Average d13C  (%0)><d13C STDEV  (%0)>0.4</d13C STDEV  (%0)><Offset from EA-IRMS d13C  (%0) xsi:nil="true" /></row>
</data>
